Response of cathodoluminescence of alkali feldspar to He+ ion implantation and electron irradiation
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Department of Earth and Planetary Systems Science, Graduate School of Science, Hiroshima University, 1-3-1 Kagami-yama, Higashi-Hiroshima, Hiroshima, 739-8526, Japan
Department of Biosphere-Geosphere Science, Okayama University of Science, 1-1 Ridaicho, Kita-ku, Okayama, Okayama, 700-0005, Japan
Department of Applied Physics, Okayama University of Science, 1-1 Ridaicho, Kita-ku, Okayama, Okayama, 700-0005, Japan
Earth Evolution Sciences, University of Tsukuba, 1-1-1 Ten-nodai, Tsukuba, Ibaraki, 305-8571, Japan
Department of Earth Sciences, University of St Andrews, Irvine Building, North Street, St Andrews, Fife, KY16 9AL, UK
School of Geographical and Earth Sciences, University of Glasgow, Lilybank Gardens, Glasgow, G12 8QQ, UK
Online publication date: 2013-09-27
Publication date: 2013-12-01
Geochronometria 2013;40(4):244-249
Cathodoluminescence (CL) of minerals such as quartz and zircon has been extensively studied to be used as an indicator for geodosimetry and geochronometry. There are, however, very few investigations on CL of other rock-forming minerals such as feldspars, regardless of their great scientific interest. This study has sought to clarify the effect of He+ ion implantation and electron irradiation on luminescent emissions by acquiring CL spectra from various types of feldspars including anorthoclase, amazonite and adularia. CL intensities of UV and blue emissions, assigned to Pb2+ and Ti4+ impurity centers respectively, decrease with an increase in radiation dose of He+ ion implantation and electron irradiation time. This may be due to decrease in the luminescence efficiencies by a change of the activation energy or a conversion of the emission center to a non-luminescent center due to an alteration of the energy state. Also, CL spectroscopy of the alkali feldspar revealed an in-crease in the blue and yellow emission intensity assigned to Al-O−-Al/Ti defect and radiation-induced defect centers with the radiation dose and the electron irradiation time. Taken together these results indicate that CL signal should be used for estimation of the α and β radiation doses from natural radionuclides that alkali feldspars have experienced.
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